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Contribution to the understanding of tribological properties of graphite intercalation compounds with metal chloride

Delbé, Karl and Mansot, Jean-Louis and Thomas, Philippe and Baranek, Philippe and Boucher, Florent and Vangelisti, Rene and Billaud, Denis Contribution to the understanding of tribological properties of graphite intercalation compounds with metal chloride. (2012) Tribology Letters, vol. 47 (n° 3). pp. 367-379. ISSN 1023-8883

(Document in English)

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Official URL: http://dx.doi.org/10.1007/s11249-012-9981-0


Intrinsic tribological properties of lamellar compounds are usually attributed to the presence of van der Waals gaps in their structure through which interlayer interactions are weak. The controlled variation of the distances and interactions between graphene layers by intercalation of electrophilic species in graphite is used in order to explore more deeply the friction reduction properties of low-dimensional compounds. Three graphite intercalation compounds with antimony pentachloride, iron trichloride and aluminium trichloride are studied. Their tribological properties are correlated to their structural parameters, and the interlayer interactions are deduced from ab initio bands structure calculations.

Item Type:Article
Additional Information:Thanks to Springer editor. The definitive version is available at www.springerlink.com. The original PDF of the article can be found at : http://dx.doi.org/10.1007/s11249-012-9981-0
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS
Other partners > EDF (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT
Other partners > Université Paul-Verlaine - Metz (FRANCE)
Other partners > Université des Antilles et de la Guyane (FRANCE)
Laboratory name:
Laboratoire Génie de Production - LGP (Tarbes, France) - Interfaces et Matériaux Fonctionnels - IMF
Groupe de technologie des surfaces et interfaces - GTSI (Pointe à Pitre, France)
EDF - R&D Department MMC and MAI (Moret sur Loing, France)
Institut des Matériaux Jean Rouxel - IMN (Nantes, France) - Stockage et de transformation électrochimiques de l'énergie - ST2E
Institut Jean Lamour - IJL (Nancy, France) - Chimie et Physique des Solides et des Surfaces - CP2S - Matériaux carbonés
Deposited By:Karl DELBE

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