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Hydroformylation of 1-Octene Using [Bmim][PF6]−Decane Biphasic Media and Rhodium Complex Catalyst: Thermodynamic Properties and Kinetic Study

Sharma, Amit and Julcour-Lebigue, Carine and Deshpande, Raj M. and Kelkar, Ashutosh A. and Delmas, Henri Hydroformylation of 1-Octene Using [Bmim][PF6]−Decane Biphasic Media and Rhodium Complex Catalyst: Thermodynamic Properties and Kinetic Study. (2010) Industrial & Engineering Chemistry Research, vol. 49 (n° 21). pp. 10698-10706. ISSN 0888-5885

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Official URL: http://dx.doi.org/10.1021/IE100222K

Abstract

A chemical reaction engineering approach is reported to investigate the biphasic hydroformylation of 1-octene using [bmim][PF6] ionic liquid. It is based both on a process parameter investigation (temperature, concentrations, and pressures) and a thermodynamic study of the reaction medium (gas−liquid and liquid−liquid equilibria). Initial rate data show complex behavior with respect to operating parameters and are best described by a rate equation based on a mechanistic model. Complete reaction scheme including isomerization is then modeled accounting from the time dependent concentration of the organic substrates measured in organic phase and recalculated in ionic liquid phase from liquid−liquid equilibria.

Item Type:Article
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT
Other partners > National Chemical Laboratory - NCL (INDIA)
Université de Toulouse > Université Paul Sabatier-Toulouse III - UPS
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Deposited By:Audrey LEFEVRE

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