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Electrochemical study in both classical cell and microreactors of flavin adenine dinucleotide as a redox mediator for NADH regeneration

Tzedakis, Theodore and Kane, Cheikhou and Roche, Jérôme and Groenen-Serrano, Karine and Reynes, Olivier Electrochemical study in both classical cell and microreactors of flavin adenine dinucleotide as a redox mediator for NADH regeneration. (2010) Electrochimica Acta, vol. 55 (n° 7). pp. 2286-2294. ISSN 0013-4686

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Official URL: http://dx.doi.org/10.1016/J.ELECTACTA.2009.11.071

Abstract

The electrochemical reduction of flavinadeninedinucleotide (FAD) is studied in a classical electrochemical cell as well as in two types of microreactors: the first one is a one-channel reactor and the other one, a multichannel filter-press reactor. The ultimate goal is to use the reduced form of flavin (FADH2), in the presence of formate dehydrogenase (FDH), in order to continuously regenerate the reduced form of nicotinamide adeninedinucleotide (NADH) for chiral syntheses. Various voltammetric and adsorption measurements were carried out for a better understanding of the redox behavior of the FAD as well as its adsorption on gold. Diffusivity and kinetic electrochemical parameters of FAD were determined.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at : http://www.sciencedirect.com/science/article/pii/S0013468609014492
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT
Université de Toulouse > Université Paul Sabatier-Toulouse III - UPS
Other partners > Ecole Supérieure Polytechnique - ESP (SENEGAL)
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Deposited By: Audrey LEFEVRE
Deposited On:04 Jun 2012 14:11

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