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A new intersecting tunnel structure in the AIMIII[PO3(OH)]2 series for AI = Ag, MIII = In : Analysis of structural relationships

Guesdon, Anne and Romero Sarria, Francesca and Tenailleau, Christophe and Raveau, Bernard A new intersecting tunnel structure in the AIMIII[PO3(OH)]2 series for AI = Ag, MIII = In : Analysis of structural relationships. (2009) Solid State Sciences, vol. 11 (n° 2). pp. 349-357. ISSN 1293-2558

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Official URL: http://dx.doi.org/10.1016/j.solidstatesciences.2008.09.015

Abstract

A new indium hydroxyphosphate containing silver, AgIn[PO3(OH)]2, has been synthesized using hydrothermal method. It crystallizes in the P21/c space group with the cell parameters a = 6.6400(2)Å, b=14.6269(6)Å, c=6.6616(4)A, β=95.681(5)°, V=643.82(6)Å3, Z=4. Its three-dimensional framework, built up of comer-sharing PO3(OH) tetrahedra and InO6 octahedra, presents intersecting tunnels running along <111> and [100] directions, in which the Ag+ cations are located. The presence of hydroxyl groups has been confirmed from IR spectroscopy studies and hydrogen atoms were located from the single crystal X-ray diffraction study. The structural relationships with the other compounds of general formula AΙΜΙΙΙ[PΟ3(OH)]2 are analyze

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Solid State Sciences website : http://www.sciencedirect.com/science/journal/12932558
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution: Université de Toulouse > Institut National Polytechnique de Toulouse - INPT
Université de Toulouse > Université Paul Sabatier-Toulouse III - UPS
Other partners > Université de Caen Basse-Normandie (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS
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Deposited By: Nihad Lahdifi
Deposited On:07 Jul 2010 11:07

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