Nourry, Christophe and Massot, Laurent and Chamelot, Pierre and Taxil, Pierre Electrochemical reduction of Gd(III) and Nd(III) on reactive cathode material in molten fluoride media. (2009) Journal of Applied Electrochemistry, vol. 3 (n° 6). pp. 927-933. ISSN 0021-891X
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Official URL: http://dx.doi.org/10.1007/s10800-008-9740-y
Abstract
The electrochemical reduction of two lanthanides (neodymium Nd and gadolinium Gd) was investigated in the 800-950°C temperature range on nickel and copper electrodes. These materials react with lanthanides (Ln) to form intermetallic compounds. The formation mechanism of these alloys was determined by coupling electrochemical techniques and Scanning Electron Microscopy (S.E.M.) after electrolyses runs; this also allowed the identification of the binary compounds formed. In addition, from the electrochemical results we calculated the Gibbs energies of Nd/Ni, Gd/Ni, Gd/Cu and Nd/Cu.
| Item Type: | Article |
|---|---|
| Additional Information: | The original publication is available at www.springerlink.com |
| Audience (journal): | International peer-reviewed journal |
| Uncontrolled Keywords: | |
| Institution: | Université de Toulouse > Institut National Polytechnique de Toulouse - INPT Université de Toulouse > Université Paul Sabatier-Toulouse III - UPS French research institutions > Centre National de la Recherche Scientifique - CNRS |
| Laboratory name: | Laboratoire de Génie Chimique - LGC (Toulouse, France) - Procédés électrochimiques (PE) |
| Statistics: | download |
| Total amount of citations (from ISI Web of Science): | 3 |
| Deposited By: | Laurent CASSAYRE |
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