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Catalytic reduction of TFSI-containing ionic liquid in the presence of lithium cations

Tułodziecki, Michal and Tarascon, Jean-Marie and Taberna, Pierre-Louis and Guéry, Claude Catalytic reduction of TFSI-containing ionic liquid in the presence of lithium cations. (2017) Electrochemistry Communications, 77. 128-132. ISSN 1388-2481

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Official URL: http://dx.doi.org/10.1016/j.elecom.2017.02.014

Abstract

The influence of the electrochemical double layer (EDL) structure on the electrochemical processes in ionic liquids is an intriguing subject. The complex layered structure of the EDL and its restructuring have been shown to strongly affect metal deposit morphology and electrochemical reaction kinetics. In this work, we demonstrate that the breakdown of an ionic liquid containing TFSI anions can be catalyzed through the addition of Li+ cations. We ascribe this catalytic effect to the change in the EDL structure: the Li+ cations preferentially adsorb on the electrode surface and drag the TFSI anions with them, facilitating their reduction. The decomposition of the ionic liquid leads to the formation of an SEI layer, which is studied using an electrochemical quartz crystal microbalance.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The original PDF of the article can be found at : http://www.sciencedirect.com/science/article/pii/S1388248117300553.
HAL Id:hal-01671204
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > Collège de France (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UPS (FRANCE)
Other partners > Université de Picardie Jules Verne (FRANCE)
Laboratory name:
Funders:
ALISTORE European Research InstituteShuting FengSamsung Advanced Institute of Technology
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Deposited By: cirimat webmestre
Deposited On:22 Dec 2017 08:14

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