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Catalytic membrane reactor for Suzuki-Miyaura C-C cross-coupling: Explanation for its high efficiency via modeling

Gu, Yingying and Bacchin, Patrice and Favier, Isabelle and Gin, Douglas L. and Lahitte, Jean-Francois and Noble, Richard D. and Gómez, Montserrat and Remigy, Jean-Christophe Catalytic membrane reactor for Suzuki-Miyaura C-C cross-coupling: Explanation for its high efficiency via modeling. ( In Press: 2016) AIChE Journal. ISSN 0001-1541

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Official URL: http://dx.doi.org/10.1002/aic.15379

Abstract

A polymeric catalytic membrane was previously prepared that showed remarkable efficiency for Suzuki-Miyaura C-C cross-coupling in a flow-through configuration. A mathematic model was developed and fitted to the experimental data to understand the significant apparent reaction rate increase exhibited by the catalytic membrane reactor compared to the catalytic system under batch reaction conditions. It appears that the high palladium nanoparticles concentration inside the membrane is mainly responsible for the high apparent reaction rate achieved. In addition the best performance of the catalytic membrane could be achieved only in the forced flow-through configuration, that, conditions permitting to the reactants be brought to the catalytic membrane by convection.

Item Type:Article
Additional Information:Thanks to John Wiley & Sons editor. The definitive version is available at http://onlinelibrary.wiley.com/ The original PDF of the article can be found at AIChE Journal website : http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1547-5905
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Université de Toulouse > Université Paul Sabatier-Toulouse III - UPS (FRANCE)
Other partners > University of Colorado at Boulder - UCB (USA)
Laboratory name:
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Deposited By: Jean-Francois LAHITTE
Deposited On:20 Jul 2016 08:50

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