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Efficient growth of sub-micrometric MOF crystals inside the channels of AAO membranes

Maksoud, Mahmoud and Roques, Nans and Brandès, Stéphane and Arurault, Laurent and Sutter, Jean-Pascal Efficient growth of sub-micrometric MOF crystals inside the channels of AAO membranes. (2013) Journal of Materials Chemistry. A, 1 (11). 3688-3693. ISSN 2050-7488

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Official URL: http://dx.doi.org/10.1039/c3ta01492d

Abstract

A dynamic step-by-step methodology has been implemented to grow the HKUST-1 porous coordination polymer inside commercial anodic aluminium oxide membranes. Efficient crystal growth is achieved from the membrane inner walls and over the whole membrane thickness when copper acetate colloidal suspensions and benzene tricarboxylic acid solutions are forced to flow through the membrane. Sorption properties of the HKUST-1 embedded in membranes show selectivity for CO2 over CO, CH4, O2 and N2 similar to the bulk material.

Item Type:Article
Additional Information:Thanks to the Royal Society of Chemistry. The definitive version is available at http://pubs.rsc.org The original PDF of the article can be found at Journal of Materials Chemistry A website : http://pubs.rsc.org/en/Content/ArticleLanding/2013/TA/c3ta01492d#!divAbstract
HAL Id:hal-01150858
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Other partners > Université de Bourgogne - UB (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UPS (FRANCE)
Laboratory name:
Funders:
Agence nationale de la recherche (France) - Université de Toulouse (France) - Région Midi-Pyrénées (France)
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Deposited By: cirimat webmestre
Deposited On:12 May 2015 07:46

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