Renault, Cyril and Roche, Jérôme and Ciumag, Mihaela Raluca and Tzedakis, Théodore and Colin, Stéphane and Serrano, Karine and Reynes, Olivier and André-Barrès, Christiane and Winterton, Peter Design and optimization of electrochemical microreactors for continuous electrosynthesis. (2012) Journal of Applied Electrochemistry, vol. 42 (n° 9). pp. 667-677. ISSN 0021-891X
|
(Document in English)
PDF ( Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 438kB |
Official URL: http://dx.doi.org/10.1007/s10800-012-0445-x
Abstract
The study focuses on the design and construction, as well as the theoretical and experimental optimization of electrochemical filter press microreactors for the electrosynthesis of molecules with a high added value. The main characteristics of these devices are firstly a high-specific electrochemical area to increase conversion and selectivity, and secondly the shape and size of themicrochannels designed for a uniform residence time distribution of the fluid. A heat exchanger is integrated into the microstructured electrode to rapidly remove (or supply) the heat required in exo- or endothermic reactions. The microreactors designed are used to perform-specific electrosynthesis reactions such as thermodynamically unfavorable reactions (continuous NADH regeneration), or reactions with high enthalpy changes.
Item Type: | Article |
---|---|
Additional Information: | Thanks to Springer editor. The original PDF of the article can be found at Journal of Applied Electrochemistry website : http://www.springer.com/chemistry/electrochemistry/journal/10800 |
HAL Id: | hal-00878979 |
Audience (journal): | International peer-reviewed journal |
Uncontrolled Keywords: | |
Institution: | French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) Université de Toulouse > Ecole nationale supérieure des Mines d'Albi-Carmaux (FRANCE) Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE) Université de Toulouse > Institut National des Sciences Appliquées de Toulouse - INSA (FRANCE) Université de Toulouse > Institut Supérieur de l'Aéronautique et de l'Espace - ISAE-SUPAERO (FRANCE) Université de Toulouse > Université Toulouse III - Paul Sabatier - UPS (FRANCE) |
Laboratory name: | |
Statistics: | download |
Deposited By: | Vincent GERBAUD |
Deposited On: | 31 Oct 2013 12:22 |
Repository Staff Only: item control page